Good news: I have reduced the total balancing resistance to 22 Ohms and that makes balancing more effective. Can bump up cells with 60 mA now and discharge with... well would have to do the arber method

(actually have done so before to measure bleed off current)
More good news: I have tested with all 16 channels and it works a treat
Bad news: One module, like said was sitting very low and I bumped it up with my lab supply. I was wiggling the banana plugs a bit and suddenly the Analog Discovery was on fire (what's that, the 5th?) and my laptop shut off. Aftermath: laptop right hand side USB connectors dead but laptop alive. Analog Discovery: dead. BMS board: Alive
Cause: the negative cable inside the power supply had wiggled loose and made contact with PE. Laptop is also on PE, Analog Discovery on PE and said negative cable was on cell 16 or about 60V and now suddenly on PE.
I have a spare right hand side sub board for the laptop back in Germany (hmm, how come?) so that's an easy fix. The AD will set me back 375€ at digikey. The inevitable cost of HW development...